Measurements of the Henry's Law Coefficients of 2-Methyl-3-buten-2-ol, Methacrolein, and Methylvinyl Ketone   总被引：1，自引：0，他引：1  

Laura T. Iraci  Bradly M. Baker  Geoffrey S. Tyndall  John J. Orlando 《Journal of Atmospheric Chemistry》1999,33(3):321-330

Using an equilibrium headspace technique, Henry's law coefficients were measured for methacrolein (H = 6.5 ± 0.7 M atm-1) and methylvinyl ketone (41 ± 7.0 M atm-1) in water at 25 °C. In addition, 2-methyl-3-buten-2-ol was studied at 30 °C in water and in an aqueous ionic solution representative of plant tissue. Similar values were found in deionized water (65 ± 3.5 M atm-1) and in a 0.05 mol kg-1 Ca2+, K+, NO3-, SO42- solution (62 ± 0.8 M atm-1). These Henry's Law coefficients are too small to allow for significant partitioning of methacrolein, methylvinyl ketone or methylbutenol into cloud water under equilibrium conditions.  相似文献   

Numerical experiments on the Rayleigh-Ritz method when applied to doubly connected plates in the case of free edge holes     

P. A. A. Laura  D. R. Avalos  H. A. Larrondo  R. E. Rossi 《Ocean Engineering》1998,25(7)

Numerical experiments are performed on the determination of the fundamental frequency of transverse vibration of simply supported rectangular plates having rectangular holes with free edges. This constitutes a rather common technological situation since holes are present in plates or slabs due to operational conditions, namely passage of conduits or ducts, electric conductors, etc., Satisfying exactly the governing natural boundary conditions at the hole edges is practically an impossible task. This study reviews numerical experiments where the displacement function is expanded into a double Fourier series which constitutes the exact solution when the plate is simply connected. Satisfactory convergence is achieved when the plate is doubly connected.  相似文献   

Quantifying Annual Nitrogen Loss to Groundwater Via Edge-of-Field Monitoring: Method and Application     

Michael Cardiff  Laura Schachter  Jake Krause  Madeline Gotkowitz  Brian Austin 《Ground water》2023,61(1):21-34

Increased nitrate concentrations in groundwater and surface waters represent one of the most widespread and acute impacts of modern agriculture on the environment. However, there is often a fundamental gap in understanding how individual agricultural fields and practices contribute to this broad-scale issue. To practically address nutrient dynamics at individual agricultural sites, methods for assessing nitrogen loss to groundwater that are minimally invasive and thus can encourage farmer “buy in” are necessary. We present an approach that uses edge-of-field monitoring at multilevel samplers along with a once-per-year tracer application (bromide) to calculate nitrogen loss on an annual basis. Using appropriate spatio-temporal integrals of measured concentrations, a net loss of nitrogen to groundwater (per field area) can be calculated. This approach directly measures impacts of nitrogen leaching below the water table, while avoiding permanent in-field installations that can interfere with farm operations. We present an application of this technique to assess nitrogen loss to groundwater over 5 years for a commercial agricultural field in Sauk County, WI. Results from Field 19 indicate that nitrogen losses are similar to (or slightly below) previously reported values for corn and potato crops. In all years, however, we estimate that more than 25% (>60 kg/ha) of nitrogen applied leached as nitrate to groundwater. Use of this mass flux estimation method was most reliable when: (1) tracer is injected directly at the water table, limiting “smearing” within the vadose zone; and (2) nitrate concentrations from laboratory analysis were obtained, rather than using ion-selective electrodes or nitrate test strips.  相似文献   

The importance of wind forcing in fjord wave modelling     

Christakos  Konstantinos  Furevik  Birgitte R.  Aarnes  Ole Johan  Breivik  Øyvind  Tuomi  Laura  Byrkjedal  Øyvind 《Ocean Dynamics》2020,70(1):57-75

Ocean Dynamics - Accurate predictions of surface ocean waves in coastal areas are important for a number of marine activities. In complex coastlines with islands and fjords, the quality of wind...  相似文献   

Buckling of circular, annular plates of non-uniform thickness     

P.A.A. Laura  R.H. Gutierrez  V. Sonzogni  S. Idelsohn 《Ocean Engineering》1997,24(1):51-61

This paper deals with the solution of the title problem in the case where the outer boundary is subjected to uniform, hydrostatic pressure while the inner edge of the plate is free. It is assumed that the plate thickness varies (a) in a discontinuous fashion and (b) linearly.An approximate approach is proposed using polynomial coordinate functions which identically satisfy the boundary conditions at the outer edge, only. The eigenvalues are determined using the optimized Rayleigh-Ritz method and good engineering agreement is shown to exist with buckling parameters obtained by means of a finite element code.  相似文献   

A GIS method to identify flat surfaces and restore relict fluvial long-profiles from terrace remnants gives new clues on how large basins respond to endorheic–exorheic transitions (Duero basin,Iberian Peninsula)     

Laura Rodríguez-Rodríguez  Loreto Antón  Raimon Pallàs  Daniel García-Castellanos  Ivone Jiménez-Munt  Candela Pastor-Martín 《地球表面变化过程与地形》2020,45(4):1013-1027

Fluvial terraces are used as geomorphic indicators for deciphering long-term landscape evolution. Knowing the distribution of fluvial terraces is essential for establishing former river profiles and their tectonic significance, for studying climate-modulated processes of terrace development, or for defining fluvial network adjustments in response to sudden base-level changes like those produced by fluvial captures. Multiple methods for automatic map production have been proposed based on the comparison of morphometric indices with those of the modern river course. Here we propose an alternative method to identify flat surfaces and scarps separating them from digital elevation models without setting comparisons with a modern river course and thus fully applicable to study flat landforms whatever their origin. Its application to the low-relief landscape of the Cenozoic Duero basin has allowed the improvement of previous geomorphological maps and the analysis of fluvial network adjustments in response to a sudden base-level fall after the opening of the Neogene endorheic basin towards the Atlantic Ocean. Reconstructed terrace long-profiles suggest an initial episode of fast vertical incision followed by a period of repeated planation–aggradation–incision with the formation of 14 to 13 unpaired terrace levels. Changes observed in the pattern of terrace profiles are discussed with regard to changes in regional tectonics and base-level variations. © 2019 John Wiley & Sons, Ltd.  相似文献   

Event-scale pebble mobility observed by RFID tracking in a pre-Alpine stream: a field laboratory     

Vladislav Ivanov  Alessio Radice  Monica Papini  Laura Longoni 《地球表面变化过程与地形》2020,45(3):535-547

Understanding coarse sediment transport is crucial for the prediction of sediment migration and the consequent development of fluvial morphologies. In this study, cobble displacements in a pre-Alpine creek have been recorded by means of radio frequency identification (RFID). Pebble monitoring has been systematically performed after each rainfall event with moderate precipitation, in order to exclude the superimposition of sediment displacements induced by triggering factors acting at different times. The analysis of the collected data was carried out through the application of both a principal component analysis and the Buckingham Π theorem. The experimental trends were interpreted considering the ratio of mobile pebbles, the pebbles' displacement and virtual velocity as the dependent variables. These quantities mostly depend on the event peak discharge, with a nonlinear increase of the travelled distance and a growth of up to two orders of magnitude of the virtual velocity (for an approximately 10× increase in peak discharge). An inverse dependency of the virtual velocity on the event duration was also observed. A comparison of the results obtained with those from laboratory investigations of bedload transport mechanics evidenced the differences in parametric trends associated with sediment mobility in the two environments. This contrast brings forward the combination of multiple drivers of sediment mobility, such as local morphology, sediment dimensions and flow unsteadiness, warranting a further in-depth investigation. Representation of results in a dimensionless form is suggested as a good practice to analyse data from case studies characterized by different scales. © 2019 John Wiley & Sons, Ltd.  相似文献   

Stratospheric entry point for upper-tropospheric air within the Asian summer monsoon anticyclone     

QiuJun Fan  JianChun Bian  Laura L. Pan 《中国科学:地球科学(英文版)》2017,60(9):1685-1693

The Asian summer monsoon (ASM) anticyclone isolates upper-tropospheric air within the interior of the anticyclone from the outside. Forward trajectory simulations in previous studies have shown that much of the air within the ASM anticyclone can be trapped for up to two or three weeks, not only laterally but also vertically. Here, we investigate the locations of exit points for upper-tropospheric air trapped within the ASM anticyclone, especially the preferred tropopause-crossing locations, using a 3-dimensional trajectory model. Forward trajectory calculations show two-thirds of the air crosses the tropopause at the southern part of the anticyclone via upward diabatic transport. Furthermore, some air crosses at northern and eastern parts via isentropic shedding, but air crosses rarely through the center of the anticyclone. However, calculations also show that many stratospheric parcels within the anticyclone are traceable from the upper-tropospheric anticyclone. This implies they cannot break through the tropopause directly overhead but instead enter the stratosphere via other entry points.  相似文献   

Individual and population indicators of Zostera japonica respond quickly to experimental addition of sediment-nutrient and organic matter     

Qiuying Han  Laura M. Soissons  Dongyan Liu  Marieke M. van Katwijk  Tjeerd J. Bouma 《Marine pollution bulletin》2017,114(1):201-209

A manipulative field experiment was designed to investigate the effects of sediment-nutrients and sediment-organic matters on seagrasses, Zostera japonica, using individual and population indicators. The results showed that seagrasses quickly responded to sediment-nutrient and organic matter loading. That is, sediment-nutrients positively impacted on seagrasses by increasing N content of leaves and roots, leaf length and belowground biomass. Sediment-organic matter loading lowered N content of seagrass leaves and belowground biomass. Negative effects of organic matter loading were aggravated during nutrient loading, by decreasing N content of leaves, P content of roots, leaf width, shoot number in the middle period of the experiment, increasing C/N ratio of leaves, C/P and N/P ratio of roots and above to belowground biomass ratio of seagrasses. Consequently, Z. japonica could be considered as a fast indicator to monitor seagrass ecosystem status in the eutrophic areas and facilitate to interpreting the response of seagrasses to multiple stressors.  相似文献   

New evidence of sea‐level lowstands and paleoenvironment during MIS 6 and 4 in the Cantabrian coastal karst: the Cobiheru cave (North Iberia)          下载免费PDF全文

Daniel Ballesteros  Laura Rodríguez‐Rodríguez  Saúl González‐Lemos  Santiago Giralt  Diego Jaime Álvarez‐Lao  Luna Adrados  Montserrat Jiménez‐Sánchez 《地球表面变化过程与地形》2017,42(11):1704-1716

The geomorphological evolution of the Cobiheru Cave shows the influence of the non‐carbonate coastal mountain ranges on coastal karst evolution, as well as the temporal distribution of the cold‐adapted fauna sites in the Cantabrian Coast. Geomorphological observation and uranium/thorium (U/Th) dating lead to the construction of an evolution model. The model comprises two episodes of cave deposition occurring at c. 60–70 and 130–150 ka, linked to cold climate conditions, global sea‐level lowstands and the erosion of alluvial fans that covered the karst. Moreover, the comparison between the Cobiheru record and some raised beaches identified in previous studies sets the beginning of the sea‐level lowering in the Cantabrian Sea during the marine isotope stages (MIS) 5–4 transition. Two palaeoenvironments are inferred based on finding Equus ferus and Elona quimperiana. A wet deciduous forest would have developed on the emerged marine terrace of the Cobiheru Cave since at least the Middle Pleistocene, and an open landscape with scarce vegetation would have been present at c. 65 ka. The erosional event identified in the Cobiheru Cave helps to understand the temporal distribution of cold‐adapted mammals located in the Asturias region. The probable sites of cold‐adapted fauna developed in caves and alluvial fans would have disappeared after 65 ka. Therefore, palaeontological and palaeoclimate research based on cold‐adapted mammals suggests the occurrence of an hiatus in the palaeontological record prior to 50 ka. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献